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Assigning oxidation numbers
Assigning oxidation numbers













  • In compounds, fluorine is assigned a −1 oxidation number oxygen is usually assigned a −2 oxidation number and hydrogen is usually assigned a +1 oxidation number.
  • Oxidation numbers are usually written with the sign first, then the magnitude, to differentiate them from charges.
  • Atoms in monatomic (i.e., one-atom) ions are assigned an oxidation number equal to their charge.
  • assigning oxidation numbers

  • Atoms in their elemental state are assigned an oxidation number of 0.
  • The rules for assigning oxidation numbers to atoms are as follows: Oxidation numbers are not necessarily equal to the charge on the atom (although sometimes they can be) we must keep the concepts of charge and oxidation numbers separate. Oxidation numbers are assigned to atoms based on four rules.

    assigning oxidation numbers

    How do we do that? We use oxidation numbers to keep track of electrons in atoms. Redox reactions require that we keep track of the electrons assigned to each atom in a chemical reaction. Chemical reactions that involve the transfer of electrons are called oxidation-reduction (or redox) reactions. So oxidation and reduction always occur together it is only mentally that we can separate them. Reduction is defined as the gain of one or more electrons by an atom. Oxidation is defined as the loss of one or more electrons by an atom. However, mentally we can separate the two processes. The process of losing and gaining electrons occurs simultaneously. This reaction involves the transfer of electrons between atoms. Somehow, the individual Mg atoms lose two electrons to make the Mg 2+ ion, while the Cl atoms gain an electron to become Cl − ions.

    assigning oxidation numbers

    The product, however, is ionic it is composed of Mg 2+ and Cl − ions. The reactants are two electrically neutral elements they have the same number of electrons as protons.

  • Recognize a reaction as an oxidation-reduction reaction.
  • Assign oxidation numbers to atoms in simple compounds.














  • Assigning oxidation numbers